Exercise it twice a year so it doesn't seize
Here's the part almost nobody does, and it's the most important. A stopcock that sits untouched for years tends to seize — the spindle furs up with limescale and corrosion, and when you finally need it in an emergency, it won't budge. We see this constantly on call-outs: the leak isn't the disaster, the stuck stopcock is.
Twice a year — say when the clocks change — give yours a workout. Turn it fully off, then fully on again, then back off a quarter-turn from fully open. That last step matters: leaving a valve cranked hard against its fully-open stop is exactly how it seizes in that position. A quarter-turn back keeps it free to move. Two minutes, twice a year, and your stopcock will actually work the day you need it.